Ok got it working. I noticed tonight that when I was using coded 414 it was showing 5 pages worth of programming but only one page was showing up on the device. I deleted the PS3 device, downloaded the new config to the URC to make sure it was really gone, then created a new device with a different name, went to the IR database and save code 414 to the device, and downloaded the new config to the URC. Works like a charm now.
Thanks to Romeo and everyone at Schmartz for the help. You all are the best.